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Hanna Instruments C 216 Instruction Manual
Hanna Instruments C 216 Instruction Manual

Hanna Instruments C 216 Instruction Manual

Multiparameter bench photometers for pool & spa applications

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Instruction Manual
C 216 & C 226
Multiparameter Bench
Photometers
for
Pool & Spa Applications
These Instruments are in
w w w . h a n n a i n s t . c o m
Compliance with the CE Directives
1

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Table of Contents
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Summary of Contents for Hanna Instruments C 216

  • Page 1 Instruction Manual C 216 & C 226 Multiparameter Bench Photometers Pool & Spa Applications These Instruments are in w w w . h a n n a i n s t . c o m Compliance with the CE Directives...
  • Page 2: Table Of Contents

    ALKALINITY ........22 WARRANTY ........51 BROMINE ........24 HANNA LITERATURE ...... 51 All rights are reserved. Reproduction in whole or in part is prohibited without the written consent of the copyright owner, Hanna Instruments Inc., Woonsocket, Rhode Island, 02895 , USA.
  • Page 3: Preliminary Examination

    PRELIMINARY EXAMINATION Please examine this product carefully. Make sure that the instrument is not damaged. If any damage occured during shipment, please notify your Dealer. Each Meter is supplied complete with: • Four Sample Cuvets and Caps • Two 9V Batteries •...
  • Page 4: General Description

    GENERAL DESCRIPTION C 99 & C 200 Series is a line of 17 different bench, microprocessor- based photometers to measure more than 50 different parameters in water and wastewater. These multipurpose meters are manufactured to measure the most important parameters of the application they have been especially designed for: C 99 Laboratories, with COD C 200 Laboratories...
  • Page 5: Significance Of Pool And Spa

    SIGNIFICANCE OF POOL AND SPA TESTING A major family leisure pursuit is the enjoyment of Swimming Pool and Spa facilities world-wide. A basic necessity of Pool water treatment, to ensure such enjoyment, is to maintain the water in a safe and pleasant condition for the bathers.
  • Page 6 between the hypochlorous acid (HOCl) and the hypochlorite ions (OCl Although both forms are considered free chlorine, it is the hypochlorous acid that provides the strongest disinfecting and oxidising characteristic of chlorine solutions. The amount of hypochlorous acid in chlorinated water dependends upon the pH value of the solution.
  • Page 7 frequently large amounts of pool water. In general its application is found just before water passes through the filter units. Its sanitizing power is not pH related. Mainly because of its strong oxidizing power the return water may contain only trace concentrations of ozone. It has to be mentioned that ozone is very unstable and there is anyway the need for low-level chlorination to ensure sanitizing throughout the whole pool.
  • Page 8 rate increases. If the alkalinity values are sufficiently high it will not be difficult to control the pH. Most pools managers do prefer to keep the pH between 7.2 and 7.4, that does ensure low corrosion rates and a sufficient activity of chlorine.
  • Page 9 Water Balance Condition of Water Recommendation 11.0 – 12.0 Corrosive Increase pH and/or Alkalinity 12.1 – 12.3 Acceptable Balance Retest water frequently 12.4 – 12.6 Ideal Balance 12.7 – 12.9 Acceptable Balance Retest water frequently 13.0 – 14.0 Scale forming Reduce pH and/or alkalinity WATER INDEX REFERENCE TABLES Temperature...
  • Page 10: Specifications

    SPECIFICATIONS Life of the instrument Light Life Light Detector Silicon Photocell Environment 0 to 50°C (32 to 122°F); max 90% RH non-condensing Power Supply 2 x 9 V batteries / 12 to 20 VDC through voltage adapter (optional) Auto-Shut off After 10' of non-use Dimensions 230 x 165 x 70 mm (9.0 x 6.5 x 2.8")
  • Page 11: Principle Of Operation

    PRINCIPLE OF OPERATION Absorption of Light is a typical phenomenon of interaction between electromagnetic radiation and matter. When a light beam crosses a substance, some of the radiation may be absorbed by atoms, molecules or crystal lattices. If pure absorption occurs, the fraction of light absorbed depends both on the optical path length through the matter and on the physical- chemical characteristics of substance according to the Lambert-Beer Law:...
  • Page 12 A microprocessor controlled special tungsten lamp emits radiation which is first optically conditioned and beamed to the sample contained in the cuvet. The optical path is fixed by the diameter of the cuvet. Then the light is spectrally filtered to a narrow spectral bandwidth, to obtain a light beam of intensity I or I.
  • Page 13: Functional Description

    FUNCTIONAL DESCRIPTION FRONT PANEL 1) Cuvet Holder 2) Dual Level Liquid Crystal Display (LCD) 3) Programs List 4) READ DIRECT, to perform measurement immediately 5) TIMER, to perform measurement after a preprogrammed countdown 6) ZERO, to zero the meter prior to measurement 7) Program , to select the desired parameter 8) ON/OFF, to turn the meter on and off...
  • Page 14: Guide To Display Codes

    GUIDE TO DISPLAY CODES Note: The secondary LCD below shows a generic "P– –", whereas the meter will indicate the exact program number (e.g. in C 216, "P1" for Alkalinity). This indicates that the meter is in a ready state and zeroing can be performed. Sampling in progress.
  • Page 15 The lamp is not working properly. Contact your dealer or the nearest Hanna Customer Service Center. The lamp is not working properly. Contact your dealer or the nearest Hanna Customer Service Center. This indicates that the meter has lost its configuration.
  • Page 16 A zero reading was not taken. Follow the instruction described in the measurement procedures for zeroing the meter. Under range. A blinking "0.00" indicates that the sample absorbs less light than the zero reference. Check the procedure and make sure that you use the same cuvet for reference (zero) and measurement.
  • Page 17: Measurement

    TIPS FOR AN ACCURATE MEASUREMENT The instructions listed below should be carefully followed during testing to ensure best accuracy. • Color or suspended matter in large amounts may cause interference, therefore, these should be removed by treatment with active carbon and by prior filtration. •...
  • Page 18 • In order to avoid reagent leaking and to obtain more accurate measurements, it is recommended to close the cuvet first with the supplied HDPE plastic stopper and then with the black cap. • Each time the cuvet is used, the cap must be tightened to the same degree.
  • Page 19: Parameters Reference Tables

    PARAMETERS REFERENCE TABLES C 216 - POOLMETER C 226 - POOLMETER Code Parameter Page Code Parameter Page 1 Alkalinity 1 Alkalinity 2 Ca Hardness 2 Bromine 3 Free Chlorine 3 Ca Hardness 4 Total Chlorine 4 Free Chlorine 5 Cyanuric Acid 5 Total Chlorine 6 pH 6 Free Copper...
  • Page 20: Operational Guide

    OPERATIONAL GUIDE POWER CONNECTION Remove the battery cover on the back of the meter; attach 2 fresh 9V batteries and replace the cover. Alternatively, plug the optional 12VDC adapter (HI 710005 - 110VDC, or HI 710006 - 220VDC) into the DC socket. Plug the adapter into the outlet.
  • Page 21 • After the desired program number appears on the secondary display, follow the measurement procedure described in the related chapter. • Select a new parameter measurement procedure by pressing the PROGRAM and PROGRAM keys. Note: in the following measurement sections, a generic "P– –" will be placed on the secondary LCD instead of the exact related message (e.g.
  • Page 22: Alkalinity

    ALKALINITY SPECIFICATIONS Range 0 to 500 mg/L (as CaCO Resolution 5 mg/L Precision ±10 @ 100 mg/L Typical EMC ±5 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 575 nm Method Colorimetric Method. At different alkalinity levels a distinctive range of colors from yellow to green and greenish blue will develop.
  • Page 23 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add carefully the content of one packet of HI 93755-0 Alkalinity Indicator Reagent. Replace the cap and shake vigorously for 30 seconds.
  • Page 24: Bromine

    BROMINE SPECIFICATIONS Range 0.00 to 10.00 mg/L Resolution 0.01 mg/L Precision ±0.05 mg/L @ 2.00 mg/L Typical EMC ±0.01 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Adaptation of the Standard Methods for the Examination of Water and Wastewater, 20 edition, DPD method.
  • Page 25 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add the content of one packet of HI 93716-0 Bromine Reagent. Replace the cap and shake gently for about 20 seconds to dissolve most of the reagent.
  • Page 26: Calcium Hardness

    CALCIUM HARDNESS SPECIFICATIONS Range 0 to 500 mg/L (as CaCO Resolution 5 mg/L Precision ±10 mg/L @ 200 mg/L Typical EMC ±5 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Colorimetric Method. The reaction between calcium and the reagents causes a violet to orange tint in the sample.
  • Page 27: Ca Hardness

    • Remove the cuvet. • Add carefully the content of one packet of HI 93756A-0 Ca Hardness 1 Reagent. Replace the cap and shake vigorously for 10 seconds. Note: Pay attention not to spill reagent otherwise full color development may be inhibithed.
  • Page 28: Free Chlorine

    FREE CHLORINE SPECIFICATIONS Range 0.00 to 5.00 mg/L Resolution 0.01 mg/L from 0.00 to 2.50 mg/L; 0.10 mg/L above 2.50 mg/L Precision ±0.03 mg/L @ 1.00 mg/L Typical EMC ±0.01 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Adaptation of the USEPA method 330.5 and...
  • Page 29 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add the content of one packet of HI 93701-0 Free Chlorine Reagent. Replace the cap and shake gently for 20 seconds.
  • Page 30: Total Chlorine

    TOTAL CHLORINE SPECIFICATIONS Range 0.00 to 5.00 mg/L Resolution 0.01 mg/L from 0.00 to 2.50 mg/L; 0.10 mg/L above 2.50 mg/L Precision ±0.03 mg/L @ 1.00 mg/L Typical EMC ±0.01 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Adaptation of the EPA method 330.5 and Standard...
  • Page 31 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add the content of one packet of HI 93711-0 Total Chlorine Reagent. Replace the cap and shake gently for 20 seconds •...
  • Page 32: Free Copper

    FREE COPPER SPECIFICATIONS Range 0.00 to 5.00 mg/L Resolution 0.01 mg/L Precision ±0.03 mg/L @ 1.00 mg/L Typical EMC ±0.01 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 575 nm Method Adaptation of the USEPA approved method. The reaction between free copper and the bicinchoninate reagent causes a purple tint in the sample.
  • Page 33 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add the content of one packet of HI 93702-0 Copper Reagent. Replace the cap and shake gently for 15 seconds.
  • Page 34: Total Copper

    TOTAL COPPER SPECIFICATIONS Range 0.00 to 5.00 mg/L Resolution 0.01 mg/L Precision ±0.03 mg/L @ 1.00 mg/L Typical EMC ±0.01 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 575 nm Method Adaptation of the USEPA approved method. The reaction between free copper and the bicinchoninate reagent causes a purple tint in the sample.
  • Page 35 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add the content of one packet of HI 93702-0 Copper Reagent. Replace the cap and shake gently for 15 seconds.
  • Page 36: Cyanuric Acid

    CYANURIC ACID SPECIFICATIONS Range 0 to 200 mg/L Resolution 1 mg/L from 0 to 100 mg/L; 10 mg/L above 100 mg/L Precision ±5 mg/L @ 60 mg/L Typical EMC ±1 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Turbidimetric method.
  • Page 37 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add the content of one packet of HI 93722-0 Cyanuric Acid Reagent. Replace the cap and shake gently for about 10 seconds (dissolution is not complete).
  • Page 38: Iron

    IRON SPECIFICATIONS Range 0.00 to 5.00 mg/L Resolution 0.01 mg/L Precision ±0.02 mg/L @ 1.50 mg/L Typical EMC ±0.01 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Adaptation of the EPA method 315B and Standard Methods for the Examination of Water and edition, 3500-Fe B.
  • Page 39 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add the content of one packet of HI 93721-0 Iron High Range Reagent. Replace the cap and shake until dissolution is complete.
  • Page 40: Ozone

    OZONE SPECIFICATIONS Range 0.00 to 2.00 mg/L Resolution 0.01 mg/L Precision ±0.03 mg/L @ 1.00 mg/L Typical EMC ±0.01 mg/L Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Colorimetric DPD Method. The reaction between ozone and the DPD reagent causes a pink tint in the sample.
  • Page 41 STANDARD MEASUREMENT PROCEDURE • Select the program number corresponding to Ozone on the secondary LCD by pressing PROGRAM • Fill the cuvet with 10 mL of unreacted 10 mL sample, up to the mark, and replace the cap. • Place the cuvet into the holder and ensure that the notch on the cap is positioned securely into the groove.
  • Page 42 ADDITIONAL MEASUREMENT PROCEDURE For samples containing chlorine • Select the program number corresponding to Ozone on the secondary LCD by pressing PROGRAM • Fill the cuvet with 10 mL of unreacted 10 mL sample, up to the mark, and replace the cap.
  • Page 43 • Press TIMER and the display will show the countdown prior to measurement. Alternatively, wait for 2 minutes and press READ DIRECT. In both cases “SIP” will blink during measurement. • The instrument directly displays a concentration value refering to chlorine interference, on the Liquid Crystal Display.
  • Page 44 SPECIFICATIONS Range 6.5 to 8.5 pH Resolution 0.1 pH Precision ±0.1 pH Typical EMC ±0.1 pH Deviation Light Source Tungsten lamp with narrow band interference filter @ 525 nm Method Adaptation of the Phenol Red method. The reaction between the sample and the reagent causes a yellow to a red tint in the sample.
  • Page 45 • Wait for a few seconds and the display will show “-0.0-”. Now the meter is zeroed and ready for measurement. • Remove the cuvet. • Add 5 drops of HI 93710-0 pH Reagent. Replace the cap and swirl the cuvet. •...
  • Page 46: Interface With Pc

    With terminal programs such as, for example, Telix , Windows Termi- ® , it is possible to remotely control your Hanna Instruments bench ® meter. Use HI 920010 cable to connect the meter to the PC, start the terminal program and set the communication options as follows: 8, N, 1, no flow control.
  • Page 47 /PUP - Program Up /PDN - Program Down /PTM - Turn Test Mode On /Brx - Set the baud rate 1 - 300 2 - 600 3 - 1200 4 - 2400 /KBL - Lock Keyboard /KBU - Unlock Keyboard ?PR# - Send Current Program Number ?BRQ - Send current baud rate 1 - 150...
  • Page 48: Standard Methods

    STANDARD METHODS Description Range Method Alcalinity 0 to 500 mg / L Colorimetric Bromine 0.00 to 10.00 mg / L Calcium Hardness 0 to 500 mg / L Colorimetric Chlorine, Free 0.00 to 5.00 mg / L Chlorine, Total 0.00 to 5.00 mg / L Copper, Free 0.00 to 5.00 mg / L Bicinchoninate...
  • Page 49: Accessories

    ACCESSORIES REAGENT SETS HI 93701-01 100 free chlorine tests (powder) HI 93701-03 300 free chlorine tests (powder) HI 93702-01 100 free copper tests HI 93702-03 300 free copper tests HI 93702T-01 100 total copper tests HI 93702T-03 300 total copper tests HI 93703-52 100 glycine powder packets (optional reagent) HI 93710-01 100 pH tests HI 93710-03 300 pH tests...
  • Page 50: Ce Declaration Of Conformity

    CE DECLARATION OF CONFORMITY Recommendations for Users Before using these products, make sure that they are entirely suitable for your specific application and for the environment in which they are used. Operation of these instruments may cause unacceptable interferences to other electronic equip- ments, this requiring the operator to take all necessary steps to correct interferences.
  • Page 51: Warranty

    If the repair is not covered by the warranty, you will be notified of the charges incurred. If the instrument is to be returned to Hanna Instruments, first obtain a Returned Goods Authorization Number from the Customer Service Department and then send it with shipment costs prepaid. When shipping any instrument, make sure it is properly packaged for complete protection.

This manual is also suitable for:

C 226

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